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Marine Geochemistry - Laboratory Methods

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Estimation of porosity from solid phase Chloride content
basics

assuming all the chloride measured in a dry marine sediment stems from the pore water chloride, the solid phase chloride content as measured from i.e. XRF may be used to estimate the porosity

equation p [%] = 100 (1+ csolution(? csolid)-1 )-1
parameters
name  unit description  typ. value
p % Vol / Vol porosity of marine sediment 70
csolution mg L-1 concentration of Cl in seawater 19354
csolid mg kg-1 concentration of Cl in dry sediment 10000
? g cm-3 density of mineral component of marine sediment 2.65
example csolution = 19354 mg L-1; csolid = 11260 mg kg-1; ? = 2.65 g cm-3:porosity = 60.7%

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